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Sulfate Free Shampoo Bar

Shampoo bars are sustainable and easy to use. They last long and are also efficient.This Shampoo bar is Sulfate free and is made of single powder surfactant SCI,which is milder and suitable for many h...

Target pH5.0 – 5.5 (Skin Safe)
PreservationBroad-Spectrum 1%
Shelf Life12 – 18 Months
Batch Scale100g to 50kg Proportional
Sulfate Free Shampoo Bar

Shampoo bars are sustainable and easy to use. They last long and are also efficient.
This Shampoo bar is Sulfate free and is made of single powder surfactant SCI,
which is milder and suitable for many hair types. It is a conditioning shampoo bar,
which doesn’t make hair dry.

 

Note on ingredients used:

 

 

Surfactants used


SCI: Sodium Cocyl Isethionate (Anionic Surfactant) – SCI is also known as baby
foam, it is gentle and milder surfactant which has good foam and rinsing properties.
Coco Betaine (Amphoteric surfactant) & Decyl glucoside (Non-ionic surfactant) –
These are the secondary surfactants which make shampoo bar more milder and
also help to solubilize SCI.

 

Conditioning ingredients:


BTMS 50- It is the popular hair conditioning ingredient. BTMS makes hair soft and
bouncy.
GHTC (Guar Hydroxypropyltrimonium Chloride)- It is also hair conditioning
ingredient which adds slip, reduces frizz.
Polyquat 7- Adds shine and reduces frizz.

 

Moisturising ingredients:


Hydrolysed Rice Protein-Hydrolysed proteins help hair look healthy. Rice water and
rice protein are widely used in hair products in certain countries.
Glycerine- is the most effective, hydrating and moisturizing ingredient.
Spirulina extract- Strong anti-oxidant which also helps hair look healthy.

 

Other ingredients:


CCTG- is a kind of natural silicone.
Cocoa butter, Stearic acid- adds conditioning properties. Also makes shampoo bar
hard. But the disadvantage in adding oils and butters is that it reduces foam. If you
don’t mind less foam, this would be your go-to shampoo bar.

 

Ingredients required:


Phase A:
SCI 85 50%
Coco Betain 10%
Decyl Glucoside 10%

Phase B:
Cocoa Butter 6.7%
BTMS 50 10%
Stearic acid 5%
CCTG 1%
GHPTC 0.2%

Phase C:
Polyquat 7 1%
Fragrance Oils 1%
Preservative Eco 1%
Hydrolysed Rice Protein 2%
Spirulina extract 0.1%
Glycerine 2%

Equipment required:


100ml glass beakers
Stirring rods and Spatulas
Heating mantle or Double boiler
Glass bottle or serum container
Weighing scale (that measures up to 0.01g)
Cups to measure ingredients
Gloves

Procedure:


1) Measure Phase A ingredients in a beaker and Phase B ingredients in another
beaker.



2) Heat both the beakers on a double boiler until emulsifiers are melted and
surfactants are dissolved. ( Do not over heat)
3) Once SCI is dissolved in surfactants and forms a paste kind of consistency,
remove the beakers from heat.


4) You could mix ingredients from both the beakers in a bowl or you can smash
and mix it with your hand.(Note: Ingredients would be at higher temperature,
so do not mix with hands. Use gloves or spatula)
5) Add cool down ingredients when it is at room temperature.
6) Take some part of the shampoo bar, test pH and adjust to 5.5.
7) Add few drops of citric acid or lactic acid if the pH is higher.
8) Mix the dough again after adding citric acid.
9) Press in a mold to shape it perfectly or shape it with your hand. Either way it
would be beautiful. Leave it for a day or two to harden.


Substitutions:


1) Other powder surfactants like SLSA, SCS can also be added along with
SCI and stearic acid, butters can be removed.
2) Extracts, Hydrolyzed Proteins and F.O can be of your choice.
3) Coco glucoside can be used in place of decyl glucoside.
4) CCTG can be substituted with dimethicone.
5) Lactic acid can be used for Glycerin


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Disclaimer: This blog is for educational and informational purposes only.

Formulation Technical Q&As & Scale-Up Guide

What is the recommended pH target for Sulfate Free Shampoo Bar?

For stable cosmetic performance, the ideal pH is between 5.0 and 5.5 for barrier and brightening serums, or 5.5 to 6.5 for hair vitality and rinse-off washes. Always test and adjust using a calibrated digital pH meter or high-accuracy test strips.

Which broad-spectrum preservative is recommended for this water-containing recipe?

Any aqueous cosmetic formulation requires broad-spectrum preservation against bacteria, yeast, and mold. We recommend 0.5%–1.0% Phenoxyethanol + Ethylhexylglycerin (Ases Preserve PHEHG) or Liquid Germall Plus, incorporated during the cool-down phase below 45°C.

What is the expected shelf life of this finished formulation?

When prepared under sanitized studio conditions with distilled water and an approved broad-spectrum preservative at proper pH, the typical shelf life is 12 to 18 months stored in airtight pump bottles below 25°C.

Can this formulation recipe be scaled up for commercial batch manufacturing?

Yes. All formulation percentages are calibrated to 100% batch weight. To scale from a 100g test sample to a 10kg or 50kg production run, multiply each ingredient weight proportionally while maintaining temperature controls and high-shear blending.

Source Professional Ingredients for This Formulation

Ekora Bazaar supplies batch-tested raw ingredients, cosmetic bases, essential oils, and packaging containers with tiered wholesale pricing and ₹90 pan-India delivery.